Over the past few decades, solar cells have become increasingly widespread, with a growing number of individuals and businesses worldwide now relying on solar energy to power their homes or operations. Energy engineers worldwide have thus been trying to identify materials that are promising for the development of photovoltaics, are eco-friendly and non-toxic, and can also be easily sourced and processed.
These include kesterite-based materials, such as Cu₂ZnSnS₄ (CZTS), a class of semiconducting materials with a crystal structure that resembles that of the naturally occurring mineral kesterite. Kesterite solar cells could have various advantages over the conventional silicon-based photovoltaics that are most used today, including lower manufacturing costs, a less toxic composition and greater flexibility.
Despite their potential, kesterite solar cells developed to date attain significantly lower power conversion efficiencies (PCEs) than their silicon counterparts. This is in great part due to atomic-scale defects in kesterite-based materials that trap charge carriers and prompt non-radiative recombination, a process that causes energy losses and thus reduces the solar cells’ performance.