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D–d/p Orbital Hybridization in Symmetry-Broken Co–Y Diatomic Sites Enables Efficient Na–S Battery

JUST PUBLISHED: JUST PUBLISHED: d–d/p Orbital Hybridization in Symmetry-Broken Co–Y Diatomic Sites Enables Efficient Na–S Battery.

Read the latest free, Open Access article from Energy Material Advances.


Despite advances of single-atom catalysts (SACs) in sodium–sulfur (Na–S) batteries, their symmetric coordination geometry (e.g., M–N4) fundamentally restricts orbital-level modulation of sulfur redox kinetics. Herein, we demonstrate that hetero-diatomic Co–Y sites with Co–N4–Y–N4 coordination on N-doped carbon (Co–Y/NC) break the M–N4 symmetry constraint through d–d orbital hybridization, which is confirmed by an implementation of advanced characterizations, including the high-angle annular dark-field scanning transmission electron microscopy and x-ray absorption fine structure spectroscopy. In practical operation, the Co–Y/NC@S cathode with 61% sulfur mass fraction delivers a superior capacity (1,109 mAh/g) at 0.2 A/g, outperforming that of Co or Y SAC and further setting a new benchmark of diatomic catalysts for Na–S battery systems.

One-of-a-kind ‘plasma tunnel’ recreates extreme conditions spacecraft face upon reentry

Picture a spacecraft returning to Earth after a long journey. The vehicle slams into the planet’s atmosphere at roughly 17,000 miles per hour. A shockwave erupts. Molecules in the air are ripped apart, forming a plasma—a gas made of charged particles that can reach tens of thousands of degrees Fahrenheit, many times hotter than the surface of the sun.

The sight is spectacular to behold, but it’s also dangerous, said Hisham Ali, assistant professor in the Ann and H.J. Smead Department of Aerospace Engineering Sciences.

The Columbia disaster is a tragic example. On Feb. 1, 2003, as the space shuttle reentered Earth’s atmosphere, plasma flooded into the vehicle through a defect in its shield of protective tiles. The shuttle disintegrated, and seven crewmembers, including CU Boulder alumna Kalpna Chawla, died.

Did we just see a black hole explode? Physicists think so—and it could explain (almost) everything

In 2023, a subatomic particle called a neutrino crashed into Earth with such a high amount of energy that it should have been impossible. In fact, there are no known sources anywhere in the universe capable of producing such energy—100,000 times more than the highest-energy particle ever produced by the Large Hadron Collider, the world’s most powerful particle accelerator. However, a team of physicists at the University of Massachusetts Amherst recently hypothesized that something like this could happen when a special kind of black hole, called a “quasi-extremal primordial black hole,” explodes.

In new research published in Physical Review Letters, the team not only accounts for the otherwise impossible neutrino but shows that the elementary particle could reveal the fundamental nature of the universe.

A new class of strange one-dimensional particles

Physicists have long categorized every elementary particle in our three-dimensional universe as being either a boson or a fermion—the former category mostly capturing force carriers like photons, the latter including the building blocks of everyday matter like electrons, protons, or neutrons. But in lower dimensions of space, the neat categorization starts to break down.

Since the ’70s, a third class capturing anything in between a fermion and a boson, dubbed anyon, has been predicted to exist—and in 2020, these odd particles were observed experimentally at the interface of supercooled, strongly magnetized, one-atom thick (that is, two-dimensional) semiconductors. And now, in two joint papers published in Physical Review A, researchers from the Okinawa Institute of Science and Technology (OIST) and the University of Oklahoma have identified a one-dimensional system where such particles can exist and explored their theoretical properties.

Thanks to the recent developments in experimental control over single particles in ultracold atomic systems, these works also set the stage for investigating the fundamental physics of tunable anyons in realistic experimental settings. “Every particle in our universe seems to fit strictly into two categories: bosonic or fermionic. Why are there no others?” asks Professor Thomas Busch of the Quantum Systems Unit at OIST.

Astronomers Reveal the Hidden Magnetic Skeleton of the Milky Way

People have scanned the night sky for ages, but some of the Milky Way’s most important features cannot be seen with ordinary light. Dr. Jo-Anne Brown, PhD, is working to chart one of those hidden ingredients: the galaxy’s magnetic field, a vast structure that can influence how gas moves, where stars form, and how cosmic particles travel.

“Without a magnetic field, the galaxy would collapse in on itself due to gravity,” says Brown, a professor in the Department of Physics and Astronomy at the University of Calgary.

“We need to know what the magnetic field of the galaxy looks like now, so we can create accurate models that predict how it will evolve.”

Real-time view inside microreactor reveals 2D semiconductor growth secrets

As the miniaturization of silicon-based semiconductor devices approaches fundamental physical limits, the electronics industry faces an urgent need for alternative materials that can deliver higher integration and lower power consumption. Two-dimensional (2D) semiconductors, which are only a single atom thick, have emerged as promising candidates due to their unique electronic and optical properties. However, despite intense research interest, controlling the growth of high-quality 2D semiconductor crystals has remained a major scientific and technological challenge.

A research team led by Research Associate Professor Hiroo Suzuki from the Department of Electrical and Communication Engineering at Okayama University, Japan, together with Dr. Kaoru Hisama from Shinshu University and Dr. Shun Fujii from Keio University, has now overcome a key barrier by directly observing how these materials grow at the atomic scale. Using an advanced in situ observation system, the researchers captured real-time images of monolayer transition metal dichalcogenides (TMDCs) forming inside a micro-confined reaction space. The study was published on December 12, 2025, in the journal Advanced Science.

The work builds on earlier success by the team in synthesizing large-area monolayer TMDC single crystals using a substrate-stacked microreactor. While that method consistently produced high-quality materials, the mechanisms governing crystal growth inside the confined space were poorly understood.

AI streamlines deluge of data from particle collisions

Scientists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory have developed a novel artificial intelligence (AI)-based method to dramatically tame the flood of data generated by particle detectors at modern accelerators. The new custom-built algorithm uses a neural network to intelligently compress collision data, adapting automatically to the density or “sparsity” of the signals it receives.

As described in a paper just published in the journal Patterns, the scientists used simulated data from sPHENIX, a particle detector at Brookhaven Lab’s Relativistic Heavy Ion Collider (RHIC), to demonstrate the algorithm’s potential to handle trillions of bits of detector data per second while preserving the fine details physicists need to explore the building blocks of matter.

The algorithm will help physicists gear up for a new era of streaming data acquisition, where every collision is recorded without pre-selecting which ones might be of interest. This will vastly expand the potential for more accurate measurements and unanticipated discoveries.

Natural magnetic materials can control light in unprecedented ways

Imagine shining a flashlight into a material and watching the light bend backward—or in an entirely unexpected direction—as if defying the law of physics. This phenomenon, known as negative refraction, could transform imaging, telecommunications, and countless other technologies. Now, a team of scientists has managed to use a natural magnetic material called CrSBr to achieve negative refraction—without the need for complicated artificial structures. The study, published in Nature Nanotechnology, opens the door to ultra-compact lenses, super-high-resolution microscopes, and reconfigurable optical devices that can be controlled with magnets.

The researchers used a very thin layer of CrSBr, a material that has a unique magnetic structure—its magnetic atoms align in different ways within and between layers. This magnetic order changes how the material interacts with light. When the magnetic order is active, it causes light to bend “the wrong way,” creating negative refraction.

By guiding light into this material on a tiny chip, the team visually confirmed the backward bending of light. They also built a miniature “hyperlens” —a device that can focus light into extremely small spots—an essential step for future high-precision imaging and data processing.

Real-time single-event position detection using high-radiation-tolerance GaN

Silicon semiconductors are widely used as particle detectors; however, their long-term operation is constrained by performance degradation in high-radiation environments. Researchers at University of Tsukuba have demonstrated real-time, two-dimensional position detection of individual charged particles using a gallium nitride (GaN) semiconductor with superior radiation tolerance.

Silicon (Si)-based devices are widely used in electrical and electronic applications; however, prolonged exposure to high radiation doses leads to performance degradation, malfunction, and eventual failure. These limitations create a strong demand for alternative semiconductor materials capable of operating reliably in harsh environments, including high-energy accelerator experiments, nuclear-reactor containment systems, and long-duration lunar or deep-space missions.

Wide-bandgap semiconductors, characterized by strong atomic bonding, offer the radiation tolerance required under such conditions. Among these materials, gallium nitride (GaN)—commonly employed in blue light-emitting diodes and high-frequency, high-power electronic devices—has not previously been demonstrated in detectors capable of two-dimensional particle-position sensing for particle and nuclear physics applications.

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